Colloquium: James Cryan
Stanford PULSE Institute
Event Details:
- Time: 3:45 - 4:45 PM
- Location: 1080 Physics Research Building
- Faculty Host: Sasha Landsman
Abstract
The ultrafast motion of electrons is a frontier problem for photochemical processes, as electron motion is a key ingredient of chemical reactions. Electronic rearrangement is also the means by which light energy is harnessed in photochemistry. The timescale for coherent electron dynamics is set by the energetic splitting of the electronic states, which in small molecular systems, is on the scale of an electron volt (eV). This sets the natural timescale for electronic motion to be few-to-sub femtosecond (fs).
To approach these extreme timescales, we can use short pulses of light to excite small quantum systems. Impulsive interactions between a light field and a quantum system can induce time-dependent oscillations in the charge density. Such electronic wavepacket motion (in the absence of nuclear motion) has come to be referred to as charge migration [1]. While the initial charge dynamics following impulsive excitation (or ionization) begins as purely electronic motion, this wavepacket will couple to other degrees of freedom in the system (i.e. nuclear motion or chemical dynamics) and lead to localization of the charge. The transfer of electronic charge across molecular bonds is fundamental to an understanding of charge transfer phenomena.
The study of these fundamental phenomena requires state-of-the-art light sources, such as the Linac Coherent Light Source (LCLS), an X-ray free electron laser (XFEL) facility which produces high-brightness, ultrashort pulses, with wavelength continuously tunable across the x-ray regime. Schemes to provide isolated, sub-femtosecond pulses from an FEL are being explored at facilities world-wide, and recently we have demonstrated such pulses at the LCLS [2], opening the door for time-resolved measurements of ultrafast electron dynamics on their natural timescale. In my talk, I will present an overview of the first experiments performed with the high average power FEL driven by the new super-conducting accelerator at SLAC. These works include exploiting the interaction between strong-laser fields and the Auger-Meitner emission from core-excited systems we can probe electronic coherence [3,4,5], attosecond pump/probe experiments of ultrafast charge dynamics following valence ionization by attosecond x-ray pulses [6] and driving x-ray nonlinearities to produce transient charge distributions [7].
[1] Cederbaum and Zobeley 1999 Chemical Physics Letters 307 205–210
[2] Duris and Li et al. 2020 Nature Photonics 14 30-36
[3] Li and Driver et al. 2022 Science 375 285-290
[4] Driver et al. 2024 Nature 632 762-767 (2024)
[5] Wang and Driver et al. Phys. Rev. X 15 011008 (2025)
[6] Driver et al. Nat. Phys. 22 1459-1466 (2026)
[7] O'Neal et al, Phys. Rev. Lett. 125, 073203 (2020)
Bio
James Cryan is an Associate Professor of Photon Science at Stanford University/SLAC National Accelerator Laboratory. James is also a member of the Stanford PULSE Institute, and the interim head of the Science, Research and Development Division of the Linac Coherent Light Source (LCLS). James received his Ph.D. in 2012 from Stanford University where he worked with Philip Bucksbaum performing the first experiments at the LCLS. His thesis work was honored by the William E. and Diane M. Spicer Young Investigator Award. After a brief period as a postdoc at Lawrence Berkeley National Laboratory, Cryan returned to SLAC as a Staff Scientist in 2014. James was elected a fellow of the American Physical Society in 2020, and became an Associate Professor in 2025.
